全文获取类型
收费全文 | 2205篇 |
免费 | 705篇 |
国内免费 | 546篇 |
专业分类
化学 | 1567篇 |
晶体学 | 33篇 |
力学 | 89篇 |
综合类 | 16篇 |
数学 | 24篇 |
物理学 | 1727篇 |
出版年
2024年 | 2篇 |
2023年 | 21篇 |
2022年 | 68篇 |
2021年 | 106篇 |
2020年 | 109篇 |
2019年 | 88篇 |
2018年 | 70篇 |
2017年 | 121篇 |
2016年 | 100篇 |
2015年 | 139篇 |
2014年 | 165篇 |
2013年 | 225篇 |
2012年 | 177篇 |
2011年 | 169篇 |
2010年 | 136篇 |
2009年 | 135篇 |
2008年 | 162篇 |
2007年 | 202篇 |
2006年 | 193篇 |
2005年 | 171篇 |
2004年 | 120篇 |
2003年 | 125篇 |
2002年 | 88篇 |
2001年 | 90篇 |
2000年 | 75篇 |
1999年 | 51篇 |
1998年 | 45篇 |
1997年 | 44篇 |
1996年 | 30篇 |
1995年 | 25篇 |
1994年 | 34篇 |
1993年 | 24篇 |
1992年 | 22篇 |
1991年 | 10篇 |
1990年 | 26篇 |
1989年 | 19篇 |
1988年 | 15篇 |
1987年 | 13篇 |
1986年 | 8篇 |
1985年 | 11篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1979年 | 3篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1959年 | 1篇 |
排序方式: 共有3456条查询结果,搜索用时 15 毫秒
1.
Rongrong Li Hongjie Peng Qingping Wu Xuejun Zhou Jiang He Hangjia Shen Minghui Yang Chilin Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(29):12227-12236
Herein, we propose the construction of a sandwich-structured host filled with continuous 2D catalysis–conduction interfaces. This MoN-C-MoN trilayer architecture causes the strong conformal adsorption of S/Li2Sx and its high-efficiency conversion on the two-sided nitride polar surfaces, which are supplied with high-flux electron transfer from the buried carbon interlayer. The 3D self-assembly of these 2D sandwich structures further reinforces the interconnection of conductive and catalytic networks. The maximized exposure of adsorptive/catalytic planes endows the MoN-C@S electrode with excellent cycling stability and high rate performance even under high S loading and low host surface area. The high conductivity of this trilayer texture does not compromise the capacity retention after the S content is increased. Such a job-synergistic mode between catalytic and conductive functions guarantees the homogeneous deposition of S/Li2Sx, and avoids thick and devitalized accumulation (electrode passivation) even after high-rate and long-term cycling. 相似文献
2.
Lithium-sulfur batteries (LSBs) with high energy density and low cost have been recognized as one of the most promising next-generation energy storage systems. Although it has taken decades of development, the practical application of LSBs has been hindered by several inherent obstacles, particularly the severe shuttle effect and sluggish reaction kinetics in the sulfur cathode. Various strategies have been proposed to address these problems via rational design of electrode materials and configurations. Freestanding sulfur cathode could be a promising strategy to improve the sulfur mass loading at the cathode level and energy density of LSBs. This minireview will briefly summary the recent advances in freestanding cathodes for LSBs. The advantages and disadvantages of various freestanding cathodes are discussed and the prospects for the development of flexible cathodes are envisioned. 相似文献
3.
Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis
Dr. Damien Dambournet Dr. Karena W Chapman Dr. Mathieu Duttine Dr. Olaf Borkiewicz Dr. Peter J Chupas Dr. Henri Groult 《ChemistryOpen》2015,4(4):443-447
The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties. 相似文献
4.
Degradation of pyrene in soil in a net-to-net pulsed discharge plasma (PDP) system was reviewed. Effect of main chemical parameters, including air flow rate, pyrene concentration, initial pH and soil moisture content on pyrene degradation was examined. The obtained results show that 87.9% of pyrene could be removed under the condition of 60 min reaction; increasing of air flow rate within 1 L min−1 was favorable for degradation; pyrene removal was decreased with the increase of initial pyrene concentration; oxidation of pyrene was more evident in acidic soil; enhancement of soil moisture content has no benefit on pyrene degradation. 相似文献
5.
Plasma-assisted flow control is of high industrial interest, but practical applications at full scale require a large surface of interaction. Nanosecond pulsed Dielectric Barrier Discharge (DBD) have demonstrated promising results of flow control, but their interacting region is limited to only a few cm2. In this paper, the conditions to extend a surface nanosecond DBD are documented. It is shown that a sliding discharge regime can fully fill an inter-electrode distance of 40 mm. This discharge regime promotes the formation of two hemispheric pressure waves originating from both air-exposed electrodes while an horizontal region of pressure gradient is also observed. 相似文献
6.
7.
空心阴极灯激发的微波等离子体炬原子/离子荧光光谱研究--钙的原子/离子荧光光谱 总被引:2,自引:0,他引:2
用强短脉冲供电技术的空心阴极灯作激发源、微波等离子体炬作原子/离子化器,建立了原子/离子荧光光谱实验装置。详细研究了微波等离子体功率、观察高度、空心阴极灯电流等因素对原子/离子荧光信号强度的影响,测量了系统对Ca的原子/离子荧光光谱的检出限。 相似文献
8.
9.
A convective flow CO laser composed of polytetrafluoroethylene discharge tubes, nickel–chromium steel components, a cupric heat exchanger and other components is described. Operating in liquid nitrogen condition, output power of 60 W has been obtained from a non-selective cavity. 相似文献
10.
非晶金刚石膜的性能及其应用 总被引:1,自引:0,他引:1
非品金刚石薄膜具有超高硬度等一系列优异的特殊性能,为工程界孜孜追求的材料表面镀膜。用百纳科技公司研发制造的过滤阴极真空电弧离子镀膜机镀制的非晶金刚石薄膜,SP^3金刚石结构量≥80%,硬度高,膜/基结合力高,摩擦系数小,耐磨损,耐腐蚀,透光率高,在电子,机械,光学,生物医学上有广泛应用前景。我们已在视窗玻璃,丝锥,模具,硬质合金刀头等产品上成功应用。 相似文献